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甲醇单溶剂合物二氯[2,2'-[1,2-亚苯基双(次氮基甲烷亚基)]二酚根合-κ(4)O,N,N',O']锰(III)

Chlorido[2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolato-κ(4) O,N,N',O']manganese(III) methanol monosolvate.

作者信息

Lin Hui, Wang Jian-Gang, Shi Hua-Tian, Chen Qun, Zhang Qian-Feng

机构信息

Institute of Molecular Engineering and Applied Chemsitry, Anhui University of Technology, Ma'anshan, Anhui 243002, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Jun 19;69(Pt 7):m404. doi: 10.1107/S1600536813016450. eCollection 2013.

DOI:10.1107/S1600536813016450
PMID:24046575
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3772432/
Abstract

In the title complex, [Mn(C20H14N2O2)Cl]·CH3OH, the central Mn(III) atom displays a distorted square-pyramidal coordination by two N and two O atoms from the tetradentate 2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idyne)]diphenolate ligand and one chloride ligand. The Mn(III) atom is 0.525 (4) Å out of the square basal N2O2 least-squares plane. The complex mol-ecule is hydrogen bonded to the methanol solvent mol-ecule.

摘要

在标题配合物[Mn(C₂₀H₁₄N₂O₂)Cl]·CH₃OH中，中心锰(III)原子通过来自四齿2,2'-[1,2-亚苯基双(次氮基甲烷基亚基)]二酚盐配体的两个氮原子和两个氧原子以及一个氯配体呈现出扭曲的四方锥配位。锰(III)原子偏离四方基底N₂O₂最小二乘平面0.525 (4) Å。配合物分子与甲醇溶剂分子形成氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2579/3772432/d06a9c2c000f/e-69-0m404-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2579/3772432/4060cd206b94/e-69-0m404-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2579/3772432/d06a9c2c000f/e-69-0m404-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2579/3772432/4060cd206b94/e-69-0m404-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2579/3772432/d06a9c2c000f/e-69-0m404-fig2.jpg

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