不对称有机催化中的双功能伯胺-硫脲。
Bifunctional primary amine-thioureas in asymmetric organocatalysis.
机构信息
Department of Chemistry and Pharmacy, Institute of Organic Chemistry 1, University of Erlangen-Nuremberg, Henkestrasse 42, 91054 Erlangen, Germany.
出版信息
Org Biomol Chem. 2013 Nov 7;11(41):7051-71. doi: 10.1039/c3ob41403e.
PMID:24057617
Abstract
Research disclosed since the demonstration of the first examples of primary amine-thiourea organocatalysis in 2006 has shown that primary amine-based thioureas can successfully catalyze a diverse variety of highly enantioselective transformations providing a wide range of versatile organic compounds. Recent remarkable progress with these chiral catalysts is summarized in this review.
摘要
自 2006 年首次展示伯胺-硫脲有机催化的实例以来，研究表明伯胺基硫脲可以成功地催化多种高度对映选择性转化，提供了广泛的多功能有机化合物。本文综述了这些手性催化剂的最新显著进展。
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