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[发光层上具有不同掺杂顺序的磷光有机发光二极管的特性]

[Properties of phosphorescent organic light-emitting diodes with different doping order on light emitting layer].

作者信息

Zhang Wei, Zhang Fang-Hui, Huang Jin

机构信息

School of Electric and Information Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2013 Jul;33(7):1763-6.

Abstract

Utilizing GIr1(green) and R-4B(red) phosphorescent dye, organic light-emitting diodes with different doping orders on red and green light-emitting layers were fabricated. The authors investigated the luminescent properties of devices combined with the effect of electron (TCTA) and hole (BCP) blocking layer. The results showed that the great impacts on spectrum, light efficiency, luminance and luminescent color were produced based on different doping order, and the authros also found the strong emission peak at the interface of the BCP and CBP layer. With the use of the red and green doping type, 0.527 mA x cm(-2), 104 cd x m(-2), 19.75 cd x A(-1) and (0.371 7, 0.576 8) could be reached, respectively. The reasons were that on the one hand, because of large difference between energy levels of host material CBP and doping material GIr1, R-4B, and charge trapping and hopping via dopants were the main mechanism of change; on the other hand, for the different energy levels between dopants and blocking layers, the doping sequence could affect barrier distribution, and then affect the electric field distribution.

摘要

利用绿色磷光染料GIr1和红色磷光染料R-4B,制备了在红色和绿色发光层具有不同掺杂顺序的有机发光二极管。作者结合电子传输层(TCTA)和空穴阻挡层(BCP)的作用研究了器件的发光特性。结果表明,不同的掺杂顺序对光谱、光效率、亮度和发光颜色产生了很大影响,作者还在BCP和CBP层的界面处发现了强发射峰。采用红绿掺杂类型时,分别可达到0.527 mA·cm⁻²、104 cd·m⁻²、19.75 cd·A⁻¹和(0.371 7,0.576 8)。原因一方面是由于主体材料CBP与掺杂材料GIr1、R-4B的能级差异较大,电荷通过掺杂剂的俘获和跳跃是主要的变化机制;另一方面,由于掺杂剂与阻挡层之间的能级不同,掺杂顺序会影响势垒分布,进而影响电场分布。

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