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石墨烯负载贵金属杂化纳米结构的合成及其作为燃料电池先进电催化剂的应用。

Synthesis of graphene-supported noble metal hybrid nanostructures and their applications as advanced electrocatalysts for fuel cells.

机构信息

State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.

出版信息

Nanoscale. 2013 Nov 21;5(22):10765-75. doi: 10.1039/c3nr03280a. Epub 2013 Sep 23.

Abstract

Graphene (GN) is an emerging carbon material that may soon find practical applications. With its unusual properties, GN is an ideal platform for constructing a series of GN-based functional nanomaterials. Among them, GN/noble metal hybrids become one of the families of composite materials with extraordinary properties by combining the advantages of noble metal nanostructures and GN. The recent progress in the synthesis of GN/noble metal hybrids is presented first, such as in situ solution based methods, electrochemical deposition methods, self-assembly and other methods. Then, the applications of these novel GN/noble metal hybrids in fuel cells are summarized and discussed. Future research trends and challenges of design and synthesis of GN/noble metal hybrids are proposed.

摘要

石墨烯(GN)是一种新兴的碳材料,可能很快就会有实际应用。GN 具有独特的性质,是构建一系列基于 GN 的功能性纳米材料的理想平台。其中,GN/贵金属杂化物通过结合贵金属纳米结构和 GN 的优势,成为具有非凡性能的复合材料家族之一。首先介绍了 GN/贵金属杂化物的合成研究进展,如原位溶液法、电化学沉积法、自组装等方法。然后总结和讨论了这些新型 GN/贵金属杂化物在燃料电池中的应用。最后提出了 GN/贵金属杂化物的设计和合成的未来研究趋势和挑战。

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