• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

有机钛（IV）氟磷酸盐的合成及[(C5Me4Et)TiF(µ-F){µ-O2P(OSiMe3)2}]2的晶体结构

Synthesis of Organotitanium(IV) Fluoride Phosphates and the Crystal Structure of [(C5Me4Et)TiF(µ-F){µ-O2P(OSiMe3)2}]2.

作者信息

Pevec Andrej, Demšar Alojz, Pinkas Jiri, Necas Marek

出版信息

Acta Chim Slov. 2012 Mar;59(1):203-6.

PMID:24061193
Abstract

The complexes [(C5Me4R)TiF(µ-F)µ-O2P(OSiMe3)2]2 [R = Me (1), Et (2)] were prepared from [(C5Me4R)TiF3]2, (R = Me, Et) and OP(OSiMe3)3. The molecular structure of 2 has been determined by single-crystal X-ray diffraction analysis. An eight-membered Ti2O4P2 metallacycle bridged by two fluorine ligands between two titanium centers is observed.

摘要

配合物[(C5Me4R)TiF(µ-F)µ-O2P(OSiMe3)2]2 [R = 甲基 (1), 乙基 (2)] 由[(C5Me4R)TiF3]2（R = 甲基、乙基）和OP(OSiMe3)3制备而成。2的分子结构已通过单晶X射线衍射分析确定。观察到在两个钛中心之间由两个氟配体桥连的八元Ti2O4P2金属环。

相似文献

1
Synthesis of Organotitanium(IV) Fluoride Phosphates and the Crystal Structure of [(C5Me4Et)TiF(µ-F){µ-O2P(OSiMe3)2}]2.有机钛（IV）氟磷酸盐的合成及[(C5Me4Et)TiF(µ-F){µ-O2P(OSiMe3)2}]2的晶体结构
Acta Chim Slov. 2012 Mar;59(1):203-6.
2
Construction of larger molecular aluminophosphate cages from the cyclic four-ring building unit.由环状四环构筑单元构建更大的分子磷酸铝笼。
Inorg Chem. 2014 Apr 7;53(7):3753-62. doi: 10.1021/ic500083a. Epub 2014 Mar 11.
3
Synthesis and Characterization of Silylated Phosphonium [P(OSiMe)] and Phosphate [OP(OSiMe)] Salts.硅烷化膦 [P(OSiMe)] 和磷酸酯 [OP(OSiMe)] 盐的合成与表征。
Inorg Chem. 2018 Aug 6;57(15):9348-9353. doi: 10.1021/acs.inorgchem.8b01323. Epub 2018 Jul 9.
4
Thermolabile Organotitanium Monoalkyl Phosphates: Synthesis, Structures, and Utility as Epoxidation Catalysts and Single-Source Precursors for TiPO.热不稳定有机钛单烷基膦酸盐：合成、结构以及作为环氧化催化剂和 TiPO 的单源前体的应用。
Inorg Chem. 2018 Jul 2;57(13):7644-7654. doi: 10.1021/acs.inorgchem.8b00611. Epub 2018 Jun 15.
5
Hexafluoroantimony(V) salts of the cationic Ti(IV) fluoride non metallocene complexes [TiF3(MeCN)3]+ and [TiF2L]2+ (L = 15-Crown-5 and 18-Crown-6). Preparation, characterization and thermodynamic stability.阳离子四价钛氟化物非茂金属配合物[TiF3(MeCN)3]+和[TiF2L]2+（L = 15-冠-5和18-冠-6）的六氟锑(V)盐。制备、表征及热力学稳定性
Dalton Trans. 2005 Sep 21(18):3039-50. doi: 10.1039/b500993f. Epub 2005 Jul 26.
6
Taking TiF4 complexes to extremes--the first examples with phosphine co-ligands.将 TiF4 配合物推向极致——首例具有膦共配体的例子。
Dalton Trans. 2010 Nov 14;39(42):10264-71. doi: 10.1039/c0dt00747a. Epub 2010 Sep 30.
7
Synthesis, characterization, and structural studies of mixed-ligand diorganotin esters, [R2Sn(OP(O)(OH)Ph)(OS(O)2R1)]n [R = n-Bu, R1 = Me (1), n-Pr(2); R = Et, R1 = Me (3)] with 1D and 3D coordination polymeric motifs.具有一维和三维配位聚合物结构单元的混合配体二有机锡酯[R2Sn(OP(O)(OH)Ph)(OS(O)2R1)]n [R = 正丁基，R1 = 甲基 (1)，正丙基(2)；R = 乙基，R1 = 甲基 (3)]的合成、表征及结构研究
Inorg Chem. 2008 Jul 7;47(13):5930-5. doi: 10.1021/ic8002433. Epub 2008 May 14.
8
The solution structures and dynamics and the solid-state structures of substituted cyclopentadienyltitanium(IV) trifluorides.取代环戊二烯基三氟化钛（IV）的溶液结构、动力学及固态结构
Inorg Chem. 2006 Sep 18;45(19):7915-21. doi: 10.1021/ic060714w.
9
Synthesis, crystal structure, and characterization of the first Nb(3) triangular cluster compound bonded to fluorine ligands: association of Nb(3)I(i)F(i)(3)F(a)(8)L(a) units and Nb(IV)L(6) Octahedra with L=O and F.首个与氟配体键合的铌（III）三角簇化合物的合成、晶体结构及表征：Nb(3)I(i)F(i)(3)F(a)(8)L(a)单元与Nb(IV)L(6)八面体（L = O和F）的缔合
Inorg Chem. 2003 Feb 24;42(4):1101-6. doi: 10.1021/ic025667w.
10
1,4-dicyanobenzene as a scaffold for the preparation of bimetallic actinide complexes exhibiting metal-metal communication.1,4-二氰基苯作为制备具有金属-金属相互作用的双金属锕系配合物的骨架。
Chemistry. 2008;14(26):7782-90. doi: 10.1002/chem.200800585.