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基于单一组分 Sm(iii) 框架和由 2,2'-联苯二甲酸和 1H-咪唑并[4,5-f][1,10]菲咯啉构建的双组分 Eu(iii)掺杂 Gd(iii) 框架的白光发射。

White light emission based on a single component Sm(iii) framework and a two component Eu(iii)-doped Gd(iii) framework constructed from 2,2'-diphenyl dicarboxylate and 1H-imidazo[4,5-f][1,10]-phenanthroline.

机构信息

Department of Chemistry, Capital Normal University, Beijing 100048, China.

出版信息

Chem Commun (Camb). 2013 Nov 14;49(88):10397-9. doi: 10.1039/c3cc46397d.

DOI:10.1039/c3cc46397d
PMID:24065041
Abstract

New 1D lanthanide-organic frameworks, [Ln(dpdc)1.5(IP)(H2O)]n (Ln = Sm 1, Eu 2, Gd 3; dpdc = 2,2'-diphenyldicarboxylate and IP = 1H-imidazo[4,5-f][1,10]-phenanthroline), were synthesized. White light emission was realized by two approaches: a single component Sm(iii) framework and a two-component Eu(iii)-doped Gd(iii) framework.

摘要

新型一维镧系有机框架，[Ln(dpdc)1.5(IP)(H2O)]n（Ln = Sm 1、Eu 2、Gd 3；dpdc = 2,2'-二苯二甲酸酯和 IP = 1H-咪唑[4,5-f][1,10] -菲咯啉），被合成。通过两种方法实现了白光发射：一种是单一成分 Sm(iii) 框架，另一种是 Eu(iii)掺杂 Gd(iii) 的二组分框架。

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