通过连续的 RAFT 单体加成合成序列可控的丙烯酸酯低聚物。
Synthesis of sequence controlled acrylate oligomers via consecutive RAFT monomer additions.
机构信息
Polymer Reaction Design Group Institute for Materials Research (IMO-IMOMEC), Universiteit Hasselt, Agoralaan Building D, B-3590 Diepenbeek, Belgium.
Nuclear Magnetic Resonance Spectroscopy Group, Institute for Materials Research (IMO-IMOMEC), Universiteit Hasselt, Agoralaan Building D, B-3590 Diepenbeek, Belgium.
出版信息
Chem Commun (Camb). 2013 Nov 14;49(88):10358-10360. doi: 10.1039/c3cc45994b.
An effective procedure to synthesize sequence controlled oligoacrylates with up to four monomer insertions via the RAFT technique is presented. Two different sets of oligomers with a preferred monomer order were synthesized. Recycling SEC allowed for facile and automated purification of the monodisperse sequence-controlled materials.
本文介绍了一种通过 RAFT 技术有效合成最多可插入四个单体的序列可控寡丙烯酸酯的方法。本文合成了两组具有优先单体顺序的不同寡聚物。通过 SEC 循环可以方便地、自动地纯化单分散的序列可控材料。
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