探究次级配位球对锌烷基氧的影响：独特的锌过氧化物物种的形成。
Probing secondary coordination sphere influence on the oxygenation of zinc alkyls: formation of a unique zinc peroxide species.
机构信息
Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie St., 50-383 Wrocław, Poland.
出版信息
Chem Commun (Camb). 2013 Nov 18;49(89):10477-9. doi: 10.1039/c3cc46206d.
PMID:24080918
Abstract
Reactions of ethylzinc derivatives of o-hydroxybiphenyl with O2 were investigated. The study revealed an essential role in the oxygenation process of intra-molecular interactions involving aromatic rings and provided a unique aryloxide (hydroxide) Zn8(OAr)8(OH)6(O2) cluster with an encapsulated peroxide species.
摘要
研究了邻羟基联苯的乙基锌衍生物与 O2 的反应。研究揭示了涉及芳环的分子内相互作用在氧合过程中的重要作用，并提供了一种独特的芳氧基（氢氧根）Zn8(OAr)8(OH)6(O2)簇，其中包含封装的过氧化物物种。
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