双（（E）-2-{3-[4-（1H-咪唑-1-基-κN（3））苯乙烯基]-5,5-二甲基-环己-2-烯基亚甲基}丙二腈）-二碘汞（II）
Bis((E)-2-{3-[4-(1H-imidazol-1-yl-κN (3))styr-yl]-5,5-di-methyl-cyclo-hex-2-enyl-idene}malono-nitrile)-diiodido-mercury(II).
作者信息
Xi Wen-Gang, Wu Zhi-Chao, Zhou Hong-Ping
机构信息
Department of Chemistry, Anhui University, Hefei 230039, People's Republic of China ; Key Laboratory of Functional Inorganic Materials, Chemistry, Hefei 230039, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 21;69(Pt 10):m548. doi: 10.1107/S1600536813025191. eCollection 2013.
In the title compound, [HgI2(C22H20N4)2], the Hg(II) cation is situated on a twofold rotation axis and is coordinated by two iodide anions and two imidazolyl N atoms in a distorted tetra-hedral geometry. In the crystal, C-H⋯I inter-actions link the mol-ecules into chains extending in [010], which are further linked into sheets parallel to (100) through C-H⋯N hydrogen bonding inter-actions.
在标题化合物[HgI₂(C₂₂H₂₀N₄)₂]中，Hg(II)阳离子位于二重旋转轴上，以扭曲的四面体几何构型由两个碘阴离子和两个咪唑基N原子配位。在晶体中，C—H⋯I相互作用将分子连接成沿[010]方向延伸的链，这些链通过C—H⋯N氢键相互作用进一步连接成平行于(100)的片层。
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