Suppr超能文献

(3S,3aS,6R,6aR)-2-氧代六氢呋喃并[3,2-b]呋喃-3,6-二基二苯甲酸酯

(3S,3aS,6R,6aR)-2-Oxohexa-hydro-furo[3,2-b]furan-3,6-diyl dibenzoate.

作者信息

Piccialli Vincenzo, Oliviero Giorgia, Zaccaria Sabrina, Centore Roberto, Tuzi Angela

机构信息

Dipartimento di Scienze Chimiche, Università degli Studi di Napoli 'Federico II', Complesso di Monte S. Angelo, Via Cinthia, 80126 Napoli, Italy.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 4;69(Pt 10):o1494-5. doi: 10.1107/S160053681302391X. eCollection 2013.

Abstract

The title compound, C20H16O7, contains a cis-fused γ-lactone tetra-hydro-furan ring system functionalized with two benzo-yloxy groups. Both rings adopt an envelope conformation. The mol-ecule assumes an elongated shape and exibits non-crystallographic C 2 symmetry. The benzo-yloxy groups are almost planar [maximum deviations of 0.0491 (15) and 0.0336 (17) Å for the O atoms] and their mean planes are inclined to one another by 16.51 (4)°. The crystal packing features weak C-H⋯O inter-actions. The aryl groups of adjacent mol-ecules are parallel shifted with face-to-face contacts and a shortest inter-molecular C⋯C distance of 3.482 (4) Å.

摘要

标题化合物C20H16O7包含一个由两个苯氧基官能化的顺式稠合γ-内酯四氢呋喃环系。两个环均呈信封构象。分子呈细长形状,并表现出非晶体学C2对称性。苯氧基几乎是平面的(O原子的最大偏差为0.0491 (15) 和0.0336 (17) Å),它们的平均平面相互倾斜16.51 (4)°。晶体堆积具有弱的C-H⋯O相互作用。相邻分子的芳基通过面对面接触平行位移,分子间最短C⋯C距离为3.482 (4) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/70c4/3790370/b8b95a0df551/e-69-o1494-fig1.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验