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2-二氯甲基-N-乙基-5-(1-苯基硅杂环戊烷-1-基)环戊-3-烯甲酰胺

2-Di-chloro-methyl-N-ethyl-5-(1-phenyl-silolan-1-yl)cyclo-pent-3-enecarboxamide.

作者信息

Xiao Han, Yang Wan-Qiu, Shen Liang

机构信息

Chemical Science and Technology Department, Kunming University, Kunming 650091, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 12;69(Pt 10):o1530. doi: 10.1107/S160053681302446X. eCollection 2013.

DOI:10.1107/S160053681302446X
PMID:24098218
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3790399/
Abstract

In the title compound, C19H25Cl2NOSi, the NH group and the carbonyl O atom of the amide fragment are involved in an inter-molecular N-H⋯O hydrogen bond forming chains of mol-ecules. The plane of the benzene ring forms a dihedral angle of 50.5 (2)° with respect to the silolane ring and an angle of 49.74 (2)° with the cyclo-pentyl moiety.

摘要

在标题化合物C₁₉H₂₅Cl₂NOSi中，酰胺片段的NH基团和羰基O原子参与分子间N-H⋯O氢键，形成分子链。苯环平面与硅杂环戊烷环形成50.5 (2)°的二面角，与环戊基部分形成49.74 (2)°的角。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b579/3790399/d304065f1c84/e-69-o1530-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b579/3790399/d304065f1c84/e-69-o1530-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b579/3790399/d304065f1c84/e-69-o1530-fig1.jpg

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