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4-Meth-oxy-anilinium 2-carb-oxy-4,5-di-chloro-benzoate.

作者信息

Smith Graham, Wermuth Urs D

机构信息

Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 18;69(Pt 10):o1546. doi: 10.1107/S1600536813025014. eCollection 2013.

Abstract

In the title salt C7H10NO(+)·C8H3Cl2O4 (-) the benzene rings of the cation and anion are essentially parallel [inter-ring dihedral angle 4.8 (2)°]. In the anion the carb-oxy-lic acid and carboxyl-ate groups make dihedral angles of 19.0 (2) and 79.5 (2)°, respectively, with the benzene ring. Aminium N-H⋯O, carb-oxy-lic acid O-H⋯O and weak aromatic C-H⋯O hydrogen-bonding associations with carboxyl O-atom acceptors together with cation-anion π-π ring inter-actions [minimum ring centroid separation = 3.734 (3) Å] give rise to a sheet structure lying parallel to (001).

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/24de/3790412/b9a053c27a23/e-69-o1546-fig1.jpg

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