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4-{(E)-[2-(吡啶-3-基羰基)肼叉基]甲基}苯基乙酸酯

4-{(E)-[2-(Pyridin-3-ylcarbon-yl)hydrazinyl-idene]meth-yl}phenyl acetate.

作者信息

Datta Riya, Ramya V, Sithambaresan M, Kurup M R Prathapachandra

机构信息

Department of Chemistry, Christ University, Hosur Road, Bangalore 560 029, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 18;69(Pt 10):o1549. doi: 10.1107/S1600536813025075. eCollection 2013.

DOI:10.1107/S1600536813025075
PMID:24098233
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3790414/
Abstract

The title compound, C15H13N3O3, exists in the E conformation with respect to the azo-methane C=N double bond. The pyridyl and phenyl rings form dihedral angles of 35.67 (8) and 36.65 (7)°, respectively with the central C(=O)N2C unit. In the crystal, N-H⋯O and C-H⋯O hydrogen bonds connect the mol-ecules into chains along the b axis. Another C-H⋯O inter-action connects mol-ecules along the c-axis direction, forming layers.

摘要

标题化合物C₁₅H₁₃N₃O₃中，偶氮甲烷C=N双键呈E构型。吡啶环和苯环与中心C(=O)N₂C单元分别形成35.67 (8)°和36.65 (7)°的二面角。在晶体中，N-H⋯O和C-H⋯O氢键将分子沿b轴连接成链。另一种C-H⋯O相互作用沿c轴方向连接分子，形成层状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/3fd73a196601/e-69-o1549-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/71e1c4dc6748/e-69-o1549-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/8d06a84e7856/e-69-o1549-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/0e61629ff987/e-69-o1549-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/3fd73a196601/e-69-o1549-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/71e1c4dc6748/e-69-o1549-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/8d06a84e7856/e-69-o1549-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/0e61629ff987/e-69-o1549-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/944f/3790414/3fd73a196601/e-69-o1549-fig4.jpg

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