Meneghetti Fiorella, Maggio Benedetta
Department of Pharmaceutical Sciences, University of Milano, via L. Mangiagalli, 25, 20133-Milano, Italy.
Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 25;69(Pt 10):o1583. doi: 10.1107/S1600536813025671. eCollection 2013.
The central eight-membered ring of the title compound, C40H36N8O2, deviates from the ideal boat conformation because the bond between the exo-ethyl-ene group and the adjacent N atom is twisted by 60.0 (4)° due to steric hindrance. Its adjacent benzene and pyrazole rings are oriented almost perpendicular to each other, making a dihedral angle of 85.8 (3)°. In the crystal, the mol-ecules are linked by C(ar)-H⋯O hydrogen bonds, generating a three-dimensional network.
标题化合物C40H36N8O2的中心八元环偏离理想的船式构象,因为由于空间位阻,外环乙烯基与相邻氮原子之间的键扭转了60.0(4)°。其相邻的苯环和吡唑环几乎相互垂直取向,二面角为85.8(3)°。在晶体中,分子通过C(芳基)-H⋯O氢键相连,形成三维网络。