（2E）-3-（2-氯-8-甲基喹啉-3-基）-1-（2,4-二甲基喹啉-3-基）丙-2-烯-1-酮
(2E)-3-(2-Chloro-8-methyl-quinolin-3-yl)-1-(2,4-di-methyl-quinolin-3-yl)prop-2-en-1-one.
作者信息
Prasath R, Sarveswari S, Ng Seik Weng, Tiekink Edward R T
机构信息
Department of Chemistry, BITS, Pilani - K. K. Birla Goa Campus, Goa 403 726, India.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Jul 20;69(Pt 8):o1275. doi: 10.1107/S1600536813019405. eCollection 2013.
In the mol-ecule of the title compound, C24H19ClN2O, the terminal quinolinyl residues are close to perpendicular to each other [dihedral angle 83.72 (4)°]. The quinolinyl residues are connected by and inclined to the prop-2-en-1-one bridge, with the Car-Car-C-C (ar = aromatic) torsion angles being 71.01 (17) and 20.6 (2)°. The crystal structure features phen-yl-carbonyl C-H⋯O inter-actions and π-π inter-actions between centrosymmetrically related quinolinyl residues [3.5341 (10) and 3.8719 (9) Å], which together lead to a three-dimensional architecture.
在标题化合物C24H19ClN2O的分子中，末端喹啉基残基彼此接近垂直[二面角83.72 (4)°]。喹啉基残基通过2-丙烯-1-酮桥相连并与之倾斜，芳基-芳基-C-C（芳基=芳族）扭转角分别为71.01 (17)°和20.6 (2)°。晶体结构具有苯基羰基C-H⋯O相互作用以及中心对称相关喹啉基残基之间的π-π相互作用[3.5341 (10)和3.8719 (9) Å]，共同形成三维结构。
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