Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China , 96 Jinzhai Road, Hefei, Anhui 230026, China, and Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University , 637371, Singapore.
Org Lett. 2013 Nov 1;15(21):5531-3. doi: 10.1021/ol402692t. Epub 2013 Oct 16.
An efficient and general method for the synthesis of conjugated dienyl ketones via palladium(II) acetate catalyzed direct cross-coupling between simple alkenes and vinyl ketones is reported. This method has been successfully applied for the synthesis of Vitamin A1 and bornelone.
本文报道了一种通过醋酸钯催化简单烯烃和乙烯基酮之间的直接交叉偶联反应高效、通用地合成共轭二烯基酮的方法。该方法已成功应用于维生素 A1 和 bornelone 的合成。
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