钯（II）催化的烯酮不对称氢膦化反应：手性三级膦的有效合成方法。
Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines.
机构信息
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
出版信息
Chem Commun (Camb). 2010 Oct 7;46(37):6950-2. doi: 10.1039/c0cc00925c. Epub 2010 Aug 23.
PMID:20730193
Abstract
Chiral tertiary phosphines were synthesized by asymmetric hydrophosphination of aromatic enones catalyzed by an organopalladium complex with high yields and stereoselectivity. The procedure offers practical access to chiral tertiary phosphines.
摘要
手性叔膦通过芳基烯酮的不对称氢膦化反应合成，由有机钯配合物催化，产率和立体选择性高。该方法为手性叔膦提供了实际的合成途径。
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