涉及金属卡宾的交叉偶联反应：从 C═C/C-C 键形成到 C-H 键官能化。
Cross-coupling reactions involving metal carbene: from C═C/C-C bond formation to C-H bond functionalization.
机构信息
Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University , Beijing 100871, China.
出版信息
J Org Chem. 2013 Oct 18;78(20):10024-30. doi: 10.1021/jo401850q. Epub 2013 Sep 19.
Cross-coupling reactions involving metal-carbene are emerging as a new type of carbon-carbon bond-forming reaction. The aim of this JOCSynopsis is to provide an overview of the most recent development of these reactions, focusing on the use of diazo compounds (or in situ formed diazo compounds from N-tosylhydrazones) as carbene precursors. In addition, the integration of this type of reaction with C-H bond functionalization is also surveyed.
涉及金属卡宾的交叉偶联反应正在成为一种新型的碳-碳键形成反应。本文的目的是概述这些反应的最新发展，重点是使用重氮化合物（或由 N-对甲苯磺酰腙原位生成的重氮化合物）作为卡宾前体。此外，还考察了这种反应与 C-H 键官能化的结合。
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