非血红素铁配合物催化卤化物氧化的机理研究。过氧化物酶与卤化酶活性。
Mechanistic insight into halide oxidation by non-heme iron complexes. Haloperoxidase versus halogenase activity.
机构信息
Department of Chemistry, Indian Institute of Technology Guwahati, Assam 781039, India.
出版信息
Chem Commun (Camb). 2013 Dec 4;49(93):10926-8. doi: 10.1039/c3cc46792a.
PMID:24136302
Abstract
This work presents the first detailed study on mechanistic aspects of halide oxidation by non-heme iron complexes. We show that while iron(III)-hydroperoxo complexes oxidise halides via oxygen atom transfer, the corresponding iron(IV)-oxo complex reacts via electron transfer.
摘要
本工作首次详细研究了非血红素铁配合物对卤化物的氧化反应的机理。我们表明，铁(III)-过氧配合物通过氧原子转移氧化卤化物，而相应的铁(IV)-氧配合物则通过电子转移反应。
Zotero 插件