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亚皮秒高强度太赫兹脉冲向液态水的超快能量传递:从头分子动力学研究。

Ultrafast energy transfer to liquid water by sub-picosecond high-intensity terahertz pulses: an ab initio molecular dynamics study.

机构信息

Center for Free-Electron Laser Science, DESY, Notkestraße 85, 22607 Hamburg (Germany); Department of Physics, University of Hamburg, Jungiusstraße 9, 20355 Hamburg (Germany); Center for Ultrafast Imaging, University of Hamburg, Luruper Chaussee 149, 22761 Hamburg (Germany) http://desy.cfel.de/cfel_theory_division/

出版信息

Angew Chem Int Ed Engl. 2013 Dec 16;52(51):13685-7. doi: 10.1002/anie.201305991. Epub 2013 Oct 23.

Abstract

Sub-picosecond heating of bulk water is accomplished by ultrashort and intense THz pulses which are able to transfer a large amount of energy to the liquid. The energy transferred corresponds to a temperature jump of about 600 K. Liquid water becomes a structureless and hot gas-like system still at the density of the liquid, in which the hydrogen-bonding structure has been washed out.

摘要

亚皮秒级的块状水体加热是通过超短和强太赫兹脉冲实现的,这些脉冲能够将大量能量传递给液体。传递的能量对应于约 600 K 的温度跃变。液态水在仍然保持液态密度的情况下变成无定形的热气体状系统,其中氢键结构已被破坏。

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