Chen Tao, Chang Qing-Rui, Liu Jing
College of Resources and Environment, Northwest A & F University, Yangling 712100, China.
Guang Pu Xue Yu Guang Pu Fen Xi. 2013 Aug;33(8):2157-62.
To acquire the accuracy distribution information of soil heavy metal, improving interpolation precision is very important for agricultural safety production and soil environment protection. In the present study, the spatial variation and Cokriging interpolation of soil Cd was studied in a sewage irrigation area. Fifty two soil samples were collected to measure the contents of soil total Cd (TCd), available Cd (ACd), pH, organic matter (OM), iron oxide (Fe2 O3) and soil reflection spectrum. Through correlation analysis, it was found that TCd and ACd had a significant correlation with soil first-order differential spectrum (-0.585** at 759 nm and -0.551** at 719 nm, respectively), which were much higher than the correlation coefficients between soil Cd contents and other environmental variables (pH, OM and Fe2O3). The spatial patterns of soil Cd were predicted by Cokriging which used soil first-order differential spectrum as covariate. Compared with the Kriging, the root-mean-square error decreased by 8.22% for TCd and 20.09% for ACd, respectively; the correlation coefficients between the predicted values and measured values increased by 27.45% for TCd and by 53.13% for ACd, respectively. Meanwhile, the prediction accuracy improved by Cokriging with soil spectrum as covariate was still higher than by Cokriging with soil environment variables (OM and Fe2O3). Therefore, it was found that Cokriging was a more accurate interpolation method which could provide more precise distribution information of soil heavy metal. At the same time, soil reflection spectrum was shown to be more economic, time-saving and easier to acquire than these usual environment variables, which indicated that soil spectrum information is more suited as a covariate used in Cokriging.
为获取土壤重金属的精度分布信息,提高插值精度对于农业安全生产和土壤环境保护至关重要。在本研究中,对某污水灌溉区土壤镉的空间变异及协同克里格插值进行了研究。采集了52个土壤样本,测定土壤总镉(TCd)、有效镉(ACd)、pH值、有机质(OM)、氧化铁(Fe2O3)及土壤反射光谱。通过相关性分析发现,TCd和ACd与土壤一阶微分光谱显著相关(分别在759 nm处为-0.585**,在719 nm处为-0.551**),这远高于土壤镉含量与其他环境变量(pH值、OM和Fe2O3)之间的相关系数。利用土壤一阶微分光谱作为协变量,通过协同克里格法预测土壤镉的空间格局。与克里格法相比,TCd的均方根误差分别降低了8.22%,ACd的均方根误差分别降低了20.09%;预测值与测量值之间的相关系数,TCd分别提高了27.45%,ACd分别提高了53.13%。同时,以土壤光谱作为协变量的协同克里格法的预测精度仍高于以土壤环境变量(OM和Fe2O3)作为协变量的协同克里格法。因此,发现协同克里格法是一种更精确的插值方法,能够提供更精确的土壤重金属分布信息。同时,土壤反射光谱比这些常用的环境变量更经济、省时且易于获取,这表明土壤光谱信息更适合作为协同克里格法中的协变量。