标记的 MIL-140A 金属有机骨架的微波辅助溶剂热合成及光学性质。
Microwave-assisted solvothermal synthesis and optical properties of tagged MIL-140A metal-organic frameworks.
机构信息
School of Chemistry, The University of Sydney , Sydney, New South Wales 2006, Australia.
出版信息
Inorg Chem. 2013 Nov 18;52(22):12878-80. doi: 10.1021/ic4024234. Epub 2013 Oct 29.
PMID:24168698
Abstract
A series of tagged MIL-140A-R frameworks have been synthesized using a microwave-assisted solvothermal method. Compared with their UiO-66-R polymorphs, the absorption energies in the MIL-140A-R series (R = NH2, NO2, Br, Cl, and F) are extended toward the visible region because of the spatial arrangement of the linkers.
摘要
使用微波辅助溶剂热法合成了一系列标记的 MIL-140A-R 框架。与它们的 UiO-66-R 多晶型物相比，由于连接体的空间排列，MIL-140A-R 系列（R = NH2、NO2、Br、Cl 和 F）的吸收能延伸到可见光区域。
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