Grup de Materials Orgànics, Institut de Nanociència i Nanotecnologia (IN2UB), Departament de Química Orgànica, Universitat de Barcelona, Martí i Franquès 1, E-08028, Barcelona, Spain.
Chem Commun (Camb). 2013 Dec 18;49(97):11427-9. doi: 10.1039/c3cc46736h.
The use of benzothiazole as an electron-withdrawing group allows obtaining the fastest thermal isomerisation kinetics reported heretofore for neutral azo dyes (70 μs at 298 K). These green light activatable molecules are valuable candidates as molecular photoswitches since they tolerate thousands of working cycles with no sign of fatigue.
苯并噻唑作为吸电子基团的使用，使得中性偶氮染料迄今为止最快的热异构化动力学成为可能（298 K 时为 70 μs）。这些绿光激活分子是有价值的分子光开关候选物，因为它们可以耐受数千个工作循环而没有疲劳的迹象。
