二氧化碳在有机分子主体中的捕获。
Carbon dioxide entrapment in an organic molecular host.
机构信息
Department of Chemistry and Polymer Science, University of Stellenbosch, Matieland, 7602, South Africa.
出版信息
Chem Commun (Camb). 2014 Jan 4;50(1):85-7. doi: 10.1039/c3cc46784h. Epub 2013 Oct 30.
PMID:24175319
Abstract
4-Phenoxyphenol crystallises to yield discrete ~60 Å(3) cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO2 pressure.
摘要
4-苯氧基苯酚结晶生成离散的~60Å(3)空腔，能够包合小分子溶剂；这些空腔由狭窄的 6 元氢键环封闭，当材料受到静态 CO2 压力时，这些潜在的孔似乎不会促进门控多孔性。
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