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一维 AgBr@Ag 纳米结构的简便合成及其可见光光催化性能。

Facile synthesis of one dimensional AgBr@Ag nanostructures and their visible light photocatalytic properties.

机构信息

School of Chemistry and Environment, Beihang University , Beijing 100191, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2013 Dec 11;5(23):12283-7. doi: 10.1021/am403349m. Epub 2013 Nov 19.

Abstract

In this work, we successfully prepared one dimensional (1D) AgBr@Ag nanostructures in high yield by a facile wet chemical method, and the plausible growth mechanism was discussed. The synthesis of as-prepared AgBr@Ag nanostructure is a dissolution and recrystallization process, and the PVP and DMSO have a synergistic and competitive effect on the preparation of 1D AgBr@Ag products. Moreover, the AgBr@Ag nanorods exhibit excellent photocatalytic activities under visible light illumination, which may be attributed to their large surface area as well as superior charge separation and transfer efficiency compared to AgBr@Ag particles.

摘要

在这项工作中,我们通过一种简单的湿化学方法成功地制备了一维(1D)AgBr@Ag 纳米结构,并且讨论了其可能的生长机制。所制备的 AgBr@Ag 纳米结构的合成是一个溶解和再结晶的过程,PVP 和 DMSO 对一维 AgBr@Ag 产物的制备具有协同和竞争作用。此外,AgBr@Ag 纳米棒在可见光照射下表现出优异的光催化活性,这可能归因于其比 AgBr@Ag 颗粒更大的比表面积以及更优的电荷分离和转移效率。

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