Umadevi M, Parimaladevi R, Sangari M
Department of Physics, Mother Teresa Women's University, Kodaikanal, Tamilnadu, India.
Department of Physics, Mother Teresa Women's University, Kodaikanal, Tamilnadu, India.
Spectrochim Acta A Mol Biomol Spectrosc. 2014;120:365-9. doi: 10.1016/j.saa.2013.10.046. Epub 2013 Oct 20.
Fluorine doped TiO2 were synthesized by solid state reaction method. Optical and structural properties of fluorine doped TiO2 were investigated by X-ray diffraction, Fourier transform infrared spectroscopy, UV-vis diffusion reflectance spectroscopy and scanning electron microscopic techniques. The prepared fluorine doped TiO2 was smaller in size with respect to pure TiO2 and it is tetragonal in crystalline structure. Nanoflakes like structure of pure and fluorine doped TiO2 was confirmed from SEM image. Fluorine doped TiO2 shows smaller band gap, high strain and dislocation density when compared to pure TiO2. It also has higher photocatalytic activity with respect to pure TiO2.
采用固相反应法合成了氟掺杂二氧化钛。通过X射线衍射、傅里叶变换红外光谱、紫外-可见漫反射光谱和扫描电子显微镜技术研究了氟掺杂二氧化钛的光学和结构性质。制备的氟掺杂二氧化钛相对于纯二氧化钛尺寸更小,晶体结构为四方晶系。扫描电子显微镜图像证实了纯二氧化钛和氟掺杂二氧化钛具有类似纳米片的结构。与纯二氧化钛相比,氟掺杂二氧化钛显示出更小的带隙、更高的应变和位错密度。它相对于纯二氧化钛也具有更高的光催化活性。