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含纳米氧化物复合材料的电物理性质

Electro-physical properties of composites with nano-sized oxides.

作者信息

Lee Sang Heon, Choi Yong

机构信息

Department of Electronic Engineering, Sunmoon University, 100 Kalsan-ri, Tangjeoung-myun, Asan, Chungnam 336-708, Korea.

出版信息

J Nanosci Nanotechnol. 2013 Nov;13(11):7610-4. doi: 10.1166/jnn.2013.7818.

Abstract

Polymer matrix nano-sized oxide composites were fabricated by using a modified injection molding in which nano-sized silicon oxide and nano-sized magnesium oxide were contained. Thermal decomposition and evaporation of organic resin depended on the composition of the composites. Nano-sized oxides were uniformly distributed in the composites produced by a modified injection molding combining vacuum degassing and curing at a moderate temperature. 0.2 wt.% of silicon oxide addition to epoxy resin showed the maximum electric field of 3.6, whereas, 2.0 wt.% of magnesium oxide addition was required to reach the same value of electrical field. Both of thermal conductivity and thermal diffusivity of the nano-sized silicon oxide-epoxy composites tended to be increased with silicon oxide content. The relative permittivity of the nano-sized silicon oxide-epoxy composites increased from 5.16 to 5.31 by adding 0.6 wt.% silicon oxide, whereas, magnesium oxide addition up to 2.0 wt.% little influenced to the permittivity. Epoxy matrix-nano-sized silicon oxide composites were more suitable than magnesium oxide for the high performance capacitance.

摘要

通过使用一种改良的注射成型工艺制备了聚合物基纳米级氧化物复合材料,其中包含纳米级氧化硅和纳米级氧化镁。有机树脂的热分解和蒸发取决于复合材料的组成。通过结合真空脱气和适度温度固化的改良注射成型工艺生产的复合材料中,纳米级氧化物均匀分布。向环氧树脂中添加0.2 wt.%的氧化硅时显示出最大电场为3.6,而需要添加2.0 wt.%的氧化镁才能达到相同的电场值。纳米级氧化硅-环氧树脂复合材料的热导率和热扩散率均倾向于随氧化硅含量的增加而提高。通过添加0.6 wt.%的氧化硅,纳米级氧化硅-环氧树脂复合材料的相对介电常数从5.16增加到5.31,而添加高达2.0 wt.%的氧化镁对介电常数影响很小。环氧基质-纳米级氧化硅复合材料比氧化镁更适合用于高性能电容。

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