Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University , Chengdu, 610064, China.
J Org Chem. 2013 Dec 6;78(23):11874-80. doi: 10.1021/jo401828b. Epub 2013 Nov 25.
An efficient, concise, and transition metal-free synthesis of functionalized sulfonylated five-membered heterocyclic compounds via an S(N)Ar reaction has been developed. Using commercially available sodium sulfinates as sulfonylation reagents, various five-membered heterocyclic sulfones were obtained in good yields.
通过 S(N)Ar 反应，开发了一种高效、简洁、无需过渡金属的官能化磺酰化五元杂环化合物的合成方法。使用市售的亚磺酸钠作为磺酰化试剂，可以以良好的产率得到各种五元杂环砜。
