基于[Bmim][PF₆]的微乳液中脂肪酶促进的 Henry 反应。

School of Chemistry, Biology and Material Science, East China Institute of Technology, Nanchang 330013, China.

Molecules. 2013 Nov 11;18(11):13910-9. doi: 10.3390/molecules181113910.

An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF6] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aromatic aldehydes, and a highest yield of 90% was obtained.

首次研究了在水/[Bmim][PF6]微乳液中进行的Henry 反应的一种环保的、酶促反应方法。米曲霉来源的支链淀粉酶对于一系列芳香醛与硝基甲烷的加成反应显示出更好的催化活性，最高产率可达 90%。