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傅里叶变换红外光谱法对大气颗粒物PM2.5中硝酸盐的定量分析

[Quantitative analysis of nitrate in atmospheric particulates PM2.5 with Fourier transform infrared spectroscopy].

作者信息

Liu Na, Wei Xiu-li, Gao Min-guang, Xu Liang, Jiao Yang, Li Sheng, Tong Jing-jing, Cheng Si-yang

机构信息

Key Laboratory of Environment Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.

出版信息

Huan Jing Ke Xue. 2013 Sep;34(9):3347-51.

Abstract

Airborne fine particulate matter PM2.5 as one of composite core pollutants of air pollution is concerned and NO as one of the main components of water-soluble ions has an important impact on precipitation and human health, so searching a method of rapid and reliable detection is an important work. According to advantages of the Fourier transform infrared spectroscopy technology, the infrared spectrum of NO3- in NH4NO3 was compared with PM2.5 by a sampling method of making film. The result shows that their spectra are consistent with each other. A range of infrared spectra of different masses of NO3- were measured and the absorbance was fitted with mass, correlation and mass range of which are 0.994 8 and 7.82-73.78 microg, respectively. According to the corresponding relationship of mass between solution and sample film, the FTIR of the sample film was measured directly and mass concentrations of NO3- in a month (between 2012-03-20 and 2012-04-20) of Hefei area are listed and the average is 4.1713 microg x m(-3).

摘要

大气细颗粒物PM2.5作为空气污染的复合核心污染物之一备受关注,而NO作为水溶性离子的主要成分之一,对降水和人体健康有重要影响,因此寻找一种快速可靠的检测方法是一项重要工作。根据傅里叶变换红外光谱技术的优势,采用制膜采样法对NH4NO3中NO3-的红外光谱与PM2.5进行了比较。结果表明它们的光谱相互一致。测量了不同质量的NO3-的一系列红外光谱,并将吸光度与质量进行拟合,其相关系数和质量范围分别为0.994 8和7.82 - 73.78微克。根据溶液与样品膜之间的质量对应关系,直接测量了样品膜的傅里叶变换红外光谱,并列出了合肥地区一个月(2012年3月20日至2012年4月20日)内NO3-的质量浓度,平均值为4.1713微克×米-3。

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