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微孔有机网络空心球:纳米 Co(3)O(4)空心氧化催化剂的有用模板。

Microporous organic network hollow spheres: useful templates for nanoparticulate Co(3)O(4) hollow oxidation catalysts.

机构信息

Department of Chemistry and Department of Energy Science, Sungkyunkwan University , Suwon 440-746, Korea.

出版信息

J Am Chem Soc. 2013 Dec 26;135(51):19115-8. doi: 10.1021/ja411263h. Epub 2013 Dec 11.

DOI:10.1021/ja411263h
PMID:24320628
Abstract

Hollow microporous organic networks (H-MONs) were prepared by a template method using silica spheres. The shell thickness was delicately controlled by changing the synthetic conditions. The H-MONs were used as a template for the synthesis of nanoparticulate Co3O4 hollows which showed excellent catalytic performance in H2O2 oxidation.

摘要

采用模板法以二氧化硅球为模板制备了中空微孔有机网络(H-MONs)。通过改变合成条件可以精细控制壳层厚度。将 H-MONs 用作合成纳米 Co3O4 空心颗粒的模板,其在 H2O2 氧化中表现出优异的催化性能。

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