Wang K, McKoy V
Annu Rev Phys Chem. 1995;46:275-304. doi: 10.1146/annurev.pc.46.100195.001423.
Rotationally resolved photoelectron spectra can provide significant insight into the underlying dynamics of molecular photoionization. Here, we discuss and compare results of recent theoretical studies of rotationally resolved photoelectron spectra with measurements for molecules such as HBr, OH, NO, N2, CO, H20, H2CO, and CH3. These studies reveal the rich dynamics of quantum-state-specific studies of molecular photoionization and provide a robust description of key spectral features resulting from Cooper minima, autoionization, alignment, partial-wave mixing, and interference in related experimental studies.
转动分辨光电子能谱能够为分子光电离的潜在动力学提供重要的见解。在此，我们讨论并比较了近期关于转动分辨光电子能谱的理论研究结果与对诸如HBr、OH、NO、N₂、CO、H₂O、H₂CO和CH₃等分子的测量结果。这些研究揭示了分子光电离量子态特异性研究中的丰富动力学，并为相关实验研究中由库珀极小值、自电离、取向、分波混合和干涉产生的关键光谱特征提供了有力的描述。
