Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene.
作者信息
Houghton Adrian Y, Karttunen Virve A, Piers Warren E, Tuononen Heikki M
机构信息
Department of Chemistry, University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada T2N 1N4.
出版信息
Chem Commun (Camb). 2014 Feb 9;50(11):1295-8. doi: 10.1039/c3cc48796b.
PMID:24345791
Abstract
The perfluorinated boraindene was synthesized and fully characterized. Both computational and crystallographic data show that is antiaromatic. Compound was shown to react reversibly with H2 and to catalyse the hydrogenation of cyclohexene. The mechanism of catalysis was probed experimentally and computationally.
摘要
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