Bailey Jonathan A, Haddow Mairi F, Pringle Paul G
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK.
Chem Commun (Camb). 2014 Feb 11;50(12):1432-4. doi: 10.1039/c3cc49000a.
Azaborinylphosphines are readily prepared by the reaction of silylphosphines with a chloroborane under mild conditions; they are shown to contain P-B bonds that are sufficiently robust to allow these ligands to be used in homogeneous catalysis.
氮杂硼膦可通过甲硅烷基膦与氯硼烷在温和条件下反应轻松制备；结果表明它们含有足够稳定的P-B键，从而使这些配体可用于均相催化。
