Deriving the colloidal synthesis of crystalline nanosheets to create self-assembly monolayers of nanoclusters.

Two-dimensional (2D) nanomaterials with the thickness at atomic level are promising candidates for a wide range of applications, and now reach the point to create diversified 2D architectures. The colloidal synthesis route is powerful to produce crystalline nanosheets, nanoribbons and nanoplatelets, and the self-assembly strategy is robust to integrate the functionalities of different nano-objects. In this review, we bridge the colloidal synthesis of nanosheets and the 2D self-assembly of nanoclusters (NCs) with the aim to further optimize the physical and chemical properties of 2D nanomaterials. Ultrasmall NCs, the intermediate for synthesizing nanosheets, are highlighted to show the similarity of 2D crystallization and 2D self-assembly. The modification of conventional 2D colloidal synthesis route greatly permits the controlled self-assembly of NCs into free-standing monolayers in colloidal solutions.