Complex single-chain polymer topologies locked by positionable twin disulfide cyclic bridges.
作者信息
Shishkan Olga, Zamfir Mirela, Gauthier Marc Andre, Börner Hans G, Lutz Jean-François
机构信息
Precision Macromolecular Chemistry Group, Institut Charles Sadron, 23 rue du Loess, BP84047, 67034 Strasbourg Cedex 2, France.
出版信息
Chem Commun (Camb). 2014 Feb 14;50(13):1570-2. doi: 10.1039/c3cc47807f.
PMID:24382604
Abstract
Oligomers containing the peptide sequence cysteine-any-cysteine (CXC) were attached, at specific locations, to a linear chain of polystyrene. The polymer-bound peptide motifs were then oxidized under dilute conditions to afford a complex bio-hybrid bi-cyclic topology via intramolecular twin disulfide bridge formation.
摘要
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