Pesticide Research Center, Michigan State University, 48824, East Lansing, Michigan.
J Chem Ecol. 1982 Jan;8(1):301-14. doi: 10.1007/BF00984025.
Field attractiveness of synthetic attractants toward males of two introduced species of sawflies was examined. It was first established that the esters of 2S,3S,7S-3, 7-dimethylpentadecan-2-ol (diprionol), which have been active toward males of manyNeodiprion species, were inactive toward males ofDiprion similis andGilpinia frutetorum, To determine the chiral combination of the alcohol moiety, four different isomers, each containing specific chirally defined carbons, were synthesized. As a result it was concluded that the most active chiral arrangement of diprionol for these species is 2S, 3R, 7R.
研究了合成引诱剂对两种引入的锯蝇雄虫的田间吸引力。首先确定，对许多 Neodiprion 种雄虫有效的 2S,3S,7S-3,7-二甲基十五烷-2-醇（双丙酯）酯对 Diprion similis 和 Gilpinia frutetorum 雄虫无效。为了确定醇部分的手性组合，合成了四个不同的异构体，每个异构体都含有特定的手性定义的碳原子。结果表明，对于这些物种，双丙酯最具活性的手性排列是 2S,3R,7R。
