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连续流动微波辅助酯交换过程的多物理场数值模拟

Multiphysics numerical modeling of the continuous flow microwave-assisted transesterification process.

作者信息

Muley Pranjali D, Boldor Dorin

机构信息

Louisiana State University Agricultural Center, Department of Biological and Agricultural Engineering, 149 EB Doran Bldg., Baton Rouge, LA 70803, USA.

出版信息

J Microw Power Electromagn Energy. 2012;46(3):139-62. doi: 10.1080/08327823.2012.11689832.

Abstract

Use of advanced microwave technology for biodiesel production from vegetable oil is a relatively new technology. Microwave dielectric heating increases the process efficiency and reduces reaction time. Microwave heating depends on various factors such as material properties (dielectric and thermo-physical), frequency of operation and system design. Although lab scale results are promising, it is important to study these parameters and optimize the process before scaling up. Numerical modeling approach can be applied for predicting heating and temperature profiles including at larger scale. The process can be studied for optimization without actually performing the experiments, reducing the amount of experimental work required. A basic numerical model of continuous electromagnetic heating of biodiesel precursors was developed. A finite element model was built using COMSOL Multiphysics 4.2 software by coupling the electromagnetic problem with the fluid flow and heat transfer problem. Chemical reaction was not taken into account. Material dielectric properties were obtained experimentally, while the thermal properties were obtained from the literature (all the properties were temperature dependent). The model was tested for the two different power levels 4000 W and 4700 W at a constant flow rate of 840ml/min. The electric field, electromagnetic power density flow and temperature profiles were studied. Resulting temperature profiles were validated by comparing to the temperatures obtained at specific locations from the experiment. The results obtained were in good agreement with the experimental data.

摘要

利用先进微波技术从植物油生产生物柴油是一项相对较新的技术。微波介电加热提高了工艺效率并缩短了反应时间。微波加热取决于多种因素,如材料特性(介电和热物理特性)、操作频率和系统设计。尽管实验室规模的结果很有前景,但在扩大规模之前研究这些参数并优化工艺非常重要。数值建模方法可用于预测加热和温度分布,包括在更大规模下的情况。可以在不实际进行实验的情况下研究该工艺以进行优化,从而减少所需的实验工作量。开发了生物柴油前体连续电磁加热的基本数值模型。使用COMSOL Multiphysics 4.2软件通过将电磁问题与流体流动和传热问题耦合建立了有限元模型。未考虑化学反应。材料的介电特性通过实验获得,而热特性则从文献中获取(所有特性均与温度有关)。该模型在840ml/min的恒定流速下针对4000W和4700W这两种不同功率水平进行了测试。研究了电场、电磁功率密度流和温度分布。通过与实验在特定位置获得的温度进行比较,验证了所得的温度分布。获得的结果与实验数据吻合良好。

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