Iijima Jun, Naruke Haruo, Takiyama Hiroshi
Department of Chemical Engineering, School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei-city, Tokyo, Japan.
Chemical Resouces Laboratory, Tokyo Institute of Technology, 4259, Nagatsuta, Midori-ku, Yokohama-city, Kanagawa, Japan.
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 19;69(Pt 11):m612-3. doi: 10.1107/S1600536813028304.
The Co(2+) ion in the title compound, Rb[Co(C3H7NO3)(H2O)5][H6CoMo6O24]·C3H7NO3·10H2O, is coordinated by five water mol-ecules and one O-monodentate l-serine ligand in a slightly distorted octahedral geometry. The Rb(+) ion is irregularly coordinated by nine O atoms. In the crystal, the H6Co(III)Mo6O24 polyanions are stacked along the b-axis direction, mediated by bridging Rb-O bonds. N-H⋯O and O-H⋯O hydrogen bonds are observed involving the l-serine mol-ecules.
标题化合物Rb[Co(C₃H₇NO₃)(H₂O)₅][H₆CoMo₆O₂₄]·C₃H₇NO₃·10H₂O中的Co(2+)离子由五个水分子和一个O-单齿L-丝氨酸配体以略微扭曲的八面体几何构型配位。Rb(+)离子由九个O原子不规则配位。在晶体中，H₆Co(III)Mo₆O₂₄多阴离子沿b轴方向堆积，由桥连的Rb-O键介导。观察到涉及L-丝氨酸分子的N-H⋯O和O-H⋯O氢键。
