Suppr超能文献

海河流域河口表层沉积物中重金属的空间分布及生态风险评价

[Spatial distribution and ecological risk assessment of heavy metals in the estuaries surface sediments from the Haihe River Basin].

作者信息

Lü Shu-Cong, Zhang Hong, Shan Bao-Qing, Li Li-Qing

机构信息

State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.

School of Environmental Studies, China University of Geosciences, Wuhan 430074, China.

出版信息

Huan Jing Ke Xue. 2013 Nov;34(11):4204-10.

Abstract

It is well known that the rivers in the Haihe River Basin have been seriously polluted. However, what is the present condition of the estuary pollution and how the polluted inland rivers affect the estuary areas are not clear. 10 main estuaries of the Haihe River Basin were selected to measure the contents of typical heavy metals (Pb, Cu, Zn, Cd, Cr and Ni) in the surface sediments and to analyze the spatial distribution of these heavy metals. The potential ecological risk index was used to assess the ecological risk of the six heavy metals in the estuaries. The results showed that the contents of Pb, Cu, Zn, Cd, Cr and Ni in the surface sediments of the 10 estuaries were all higher than their background values in the main local soil types and the contents of Cu, Ni and Pb were 2.3-2.6 times as high as their background values, which indicated that the estuaries were contaminated by the six heavy metals. The results also indicated that the contents of the six heavy metals in surface sediment varied from one estuary to another. The four heavy metals of Cr, Cu, Ni and Zn had bigger spatial differences than Pb and Cd in the contents in sediment from different estuaries. The contents of Cr, Cu, Ni and Zn in sediment were higher in the estuaries of the Yongdingxin River, Ziyaxin River and Beipai River than those in the other estuaries, and there were significant correlations between each other (R(Cu-Zn) = 0.891, R(Cu-Cr) = 0.927, R(Cu-Ni) = 0.964, R(Zn-Cr) = 0.842, R(Zn-Ni) = 0.939, and R(Cr-Ni) = 0.879, P < 0.01), which indicated that they possibly came from the same sources. Moreover, the contents of Cr, Cu, Ni and Zn in sediment also had significant correlations with the populations of sub-river basins with correlation coefficients of 0.855, 0.806, 0.867 and 0.855 (P < 0.01), respectively. The contents of Cd and Pb had smaller spatial differences in sediment from different estuaries than the other heavy metals, with the values ranged 23.3-95.8 mg x kg(-1) and 0.051-0.200 mg x kg(-1). Contents of the two heavy metals had no significant correlation with the other heavy metals or with the populations of sub-river basins, indicating that Cd and Pb had little connection with the in-land polluted sources. The results of ecological risk assessment showed that estuaries of the Haihe River Basin had the potential ecological risk at lower levels (RI were 33.7-116) and the most important contaminating element was Cd with a middle-level potential ecological risk (Er(i) were 18.0-48.9).

摘要

众所周知,海河流域的河流已受到严重污染。然而,河口污染的现状以及受污染的内陆河流如何影响河口地区尚不清楚。选取海河流域10个主要河口,测定表层沉积物中典型重金属(铅、铜、锌、镉、铬和镍)的含量,并分析这些重金属的空间分布。采用潜在生态风险指数评估河口六种重金属的生态风险。结果表明,10个河口表层沉积物中铅、铜、锌、镉、铬和镍的含量均高于当地主要土壤类型的背景值,其中铜、镍和铅的含量是其背景值的2.3 - 2.6倍,表明河口受到这六种重金属的污染。结果还表明,表层沉积物中六种重金属的含量因河口而异。在不同河口沉积物中,铬、铜、镍和锌四种重金属含量的空间差异比铅和镉大。永定新河、子牙新河和北排河河口沉积物中铬、铜、镍和锌的含量高于其他河口,且它们之间存在显著相关性(R(铜 - 锌)= 0.891,R(铜 - 铬)= 0.927,R(铜 - 镍)= 0.964,R(锌 - 铬)= 0.842,R(锌 - 镍)= 0.939,R(铬 - 镍)= 0.879,P < 0.01),这表明它们可能来自同一来源。此外,沉积物中铬、铜、镍和锌的含量与子流域人口也存在显著相关性,相关系数分别为0.855、0.806、0.867和0.855(P < 0.01)。镉和铅在不同河口沉积物中的空间差异比其他重金属小,含量范围分别为23.3 - 95.8 mg·kg⁻¹和0.051 - 0.200 mg·kg⁻¹。这两种重金属的含量与其他重金属或子流域人口均无显著相关性,表明镉和铅与内陆污染源的联系较小。生态风险评估结果表明,海河流域河口存在较低水平的潜在生态风险(RI为33.7 - 116),最重要的污染元素是镉,具有中等水平的潜在生态风险(Er(i)为18.0 - 48.9)。

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验