Zhou Xiao-Hong, Liu Long-Mei, Chen Xi, Chen Zhi-Gang, Zhang Jin-Ping, Li Yi-Min, Liu Biao
Huan Jing Ke Xue. 2014 Nov;35(11):4127-34.
In order to reveal the pollution loading of heavy metals in Dammed Jinshan lake, six heavy metals (As, Cu, Pb, Cd, Zn, Cr) from 18 sediment samples were analyzed using ICP, and the distribution characteristics of heavy metals in the sediment were comprehensively evaluated through concentration coefficient, geo-acumulation indexes, potential ecological risk evaluation and traceability analysis. The results showed that (1) the average contents of As, Pb, Cu, Zn, Cr, Cd were 23.22, 26.20, 24.42, 143.12, 245.30 and 0.67 mg x kg(-1), respectively, in the surface sediments of dammed Jinshan Lake. The average contents of Pb and Cu were lower than the primary standard and secondary standards of soil environmental quality standards. The average contents of Zn and Cr were lower than the primary standard and higher than the secondary standards of soil environmental quality standards. The average contents of As and Cd were higher than the primary and secondary standards of soil environmental quality standards. From the spatial distribution, the contents of Pb and Zn were the highest at sampling site No. 1, which was located at the Beigushan Square. The contents of As,Cu, Cr, Cd were the highest at sampling sites Nos. 12, 3, 14, and 7, respectively; (2) The order of concentration coefficient was As > Cr > Cd > Pb > Zn > Cu, which indicated that the enrichment amount of As was the highest and that of Cu was the lowest; (3) Based on the geo-acumulation indexes, the Cu is clean and Pb, Zn, Cd is the light pollution and As, Cr moderate pollution; (4) The order of Potential ecological risk coefficient was Cd > As > Cr > Pb > Cu > Zn, Cr, Pb, Cu, Zn were of light ecological risk and As, Cd were of medium ecological risk. From the spatial distribution, the sampling sites Nos. 1, 6, 7 and 12 had medium potential ecological risk, and the rest sample points had slight potential ecological risk; (5) The principal component analysis (PCA) revealed that the main reason for the differences of heavy metals in surface sediments of Jinshan lake was the different sediment environmental background value at the 18 samples sites. Besides, the pollution sources in each sampling sites also contributed to the differences in heavy metals; (6) the influence of the dam on the heavy metals distribution was not clear, and requires long-term study.
为揭示水坝建成后的金山湖重金属污染负荷,采用电感耦合等离子体质谱仪(ICP)对18个沉积物样品中的6种重金属(砷、铜、铅、镉、锌、铬)进行了分析,并通过富集系数、地累积指数、潜在生态风险评价和溯源分析对沉积物中重金属的分布特征进行了综合评价。结果表明:(1)水坝建成后的金山湖表层沉积物中,砷、铅、铜、锌、铬、镉的平均含量分别为23.22、26.20、24.42、143.12、245.30和0.67mg·kg-1。铅和铜平均含量低于土壤环境质量标准一级标准和二级标准;锌和铬平均含量低于土壤环境质量标准一级标准,但高于二级标准;砷和镉平均含量高于土壤环境质量标准一级和二级标准。从空间分布来看,位于北固山广场的1号采样点铅和锌含量最高;砷、铜、铬、镉含量分别在12号、3号、14号和7号采样点最高;(2)富集系数顺序为砷>铬>镉>铅>锌>铜,表明砷的富集量最高,铜的富集量最低;(3)根据地累积指数,铜为清洁,铅、锌、镉为轻度污染,砷、铬为中度污染;(4)潜在生态风险系数顺序为镉>砷>铬>铅>铜>锌,铬、铅、铜、锌为轻度生态风险,砷、镉为中度生态风险。从空间分布来看,1号、6号、7号和12号采样点具有中等潜在生态风险,其余采样点具有轻微潜在生态风险;(5)主成分分析(PCA)表明,金山湖表层沉积物中重金属差异的主要原因是18个采样点沉积物环境背景值不同。此外,各采样点的污染源也导致了重金属的差异;(6)水坝对重金属分布的影响不明确,需要长期研究。