Department of Engineering Science, The University of Electro-Communications, Chofu, Tokyo 182-8585, Japan.
Chem Commun (Camb). 2014 Mar 7;50(19):2529-31. doi: 10.1039/c3cc48326f. Epub 2014 Jan 27.
The intramolecular radical-Gd antiferromagnetic coupling (2J1/k(B) = -11.6 K) is notably strong, as expected from our molecular design, and the intermolecular exchange coupling along the Gd-O-H···O-Gd bridges is unexpectedly ferromagnetic with the largest Gd···Gd coupling ever known (2J2/k(B) = +0.12 K).
分子内自由基-Gd 反铁磁耦合（2J1/k(B) = -11.6 K）非常强，这与我们的分子设计预期相符，而沿 Gd-O-H···O-Gd 桥的分子间交换耦合出人意料地呈铁磁性，具有已知的最大 Gd···Gd 耦合（2J2/k(B) = +0.12 K）。
