6-乙烯基富烯的简便合成
An expedient synthesis of 6-vinylfulvene.
作者信息
Erden Ihsan, Sabol Jenny, Gubeladze Ana, Ruiz Andrea
机构信息
Department of Chemistry and Biochemistry, San Francisco State University, San Francisco, CA, USA.
出版信息
Turk J Chem. 2013 Aug 13;37(4):519-524.
Abstract
6-Vinylfulvenes constitute a class of fulvenes that are difficult to access due to the lack of a general method for their synthesis. In particular, the unsubstituted parent system has been very difficult to obtain by existing methods. In this communication we describe a convenient 3-step protocol for the synthesis of the title compound by way of sulfide oxidation and subsequent sulfoxide elimination.
摘要
6-乙烯基富烯是一类由于缺乏通用合成方法而难以制备的富烯。特别是，未取代的母体体系通过现有方法一直很难获得。在本通讯中，我们描述了一种通过硫化物氧化及随后的亚砜消除反应来合成标题化合物的简便三步方法。
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Tetrahedron. 2013 Jun 17;69(24):5044-5047. doi: 10.1016/j.tet.2013.03.053.
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An exceptionally simple and efficient synthesis of 6-methyl-6-vinylfulvene, and its oxidative transformations.6-甲基-6-乙烯基富烯的一种极其简单高效的合成方法及其氧化转化反应。
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