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利用降尘滤膜作为被动采样器来监测污染矿山尾矿附近社区空气中的金属浓度。

Use of dust fall filters as passive samplers for metal concentrations in air for communities near contaminated mine tailings.

机构信息

Environmental Health Sciences, Mel and Enid Zuckerman College of Public Health, University of Arizona, 1295 N Martin Ave., PO Box 245210, Tucson, USA.

出版信息

Environ Sci Process Impacts. 2014 May;16(6):1275-81. doi: 10.1039/c3em00626c.

Abstract

Mine tailings are a source of metal exposures in many rural communities. Multiple air samples are necessary to assess the extent of exposures and factors contributing to these exposures. However, air sampling equipment is costly and requires trained personnel to obtain measurements, limiting the number of samples that can be collected. Simple, low-cost methods are needed to allow for increased sample collection. The objective of our study was to assess if dust fall filters can serve as passive air samplers and be used to characterize potential exposures in a community near contaminated mine tailings. We placed filters in cylinders, concurrently with active indoor air samplers, in 10 occupied homes. We calculated an estimated flow rate by dividing the mass on each dust fall filter by the bulk air concentration and the sampling duration. The mean estimated flow rate for dust fall filters was significantly different during sampling periods with precipitation. The estimated flow rate was used to estimate metal concentration in the air of these homes, as well as in 31 additional homes in another rural community impacted by contaminated mine tailings. The estimated air concentrations had a significant linear association with the measured air concentrations for beryllium, manganese and arsenic (p < 0.05), whose primary source in indoor air is resuspended soil from outdoors. In the second rural community, our estimated metal concentrations in air were comparable to active air sampling measurements taken previously. This passive air sampler is a simple low-cost method to assess potential exposures near contaminated mining sites.

摘要

矿山尾矿是许多农村社区金属暴露的来源。为了评估暴露程度和导致这些暴露的因素,需要采集多个空气样本。然而,空气采样设备昂贵,需要经过培训的人员进行测量,这限制了可采集样本的数量。需要简单、低成本的方法来增加样本采集量。我们的研究目的是评估尘埃降落在污染的矿山尾矿附近的社区中是否可以作为被动空气采样器,用于描述潜在的暴露情况。我们将过滤器放置在圆柱体中,与室内空气主动采样器同时放置在 10 个居住的房屋中。我们通过将每个尘埃降落在过滤器上的质量除以空气的总体浓度和采样持续时间来计算估计的流速。在有降水的采样期间,尘埃降落在过滤器上的估计流速明显不同。使用估计的流速来估算这些房屋以及另一个受污染矿山尾矿影响的农村社区的 31 个额外房屋空气中的金属浓度。估计的空气浓度与铍、锰和砷的实测空气浓度呈显著线性关系(p<0.05),其室内空气中的主要来源是室外重新悬浮的土壤。在第二个农村社区,我们对空气中的金属浓度的估计与以前进行的主动空气采样测量相当。这种被动空气采样器是一种简单、低成本的方法,可以评估受污染矿区附近的潜在暴露情况。

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