Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University , 200433, Shanghai, P. R. China.
J Am Chem Soc. 2014 Feb 26;136(8):2982-5. doi: 10.1021/ja412667t. Epub 2014 Feb 17.
A chelation-directed self-sorting synthesis of a series of cationic heterometallic coordination cages (HCCs) with tunable sizes is described. Two complexation modes were found in the cage-forming process. Metal-anchoring host-guest behavior and size-selective in-cage catalytic activities were found for the HCCs.
一种由螯合导向的、一系列具有可调尺寸的阳离子杂金属配位笼（HCCs）的自分拣合成方法被描述。在笼形成过程中发现了两种络合模式。对于 HCCs，发现了金属锚定主客体行为和尺寸选择性的笼内催化活性。
