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吡啶氮氧化物-BF₂CF₃配合物的合成及其荧光性质。

Synthesis of pyridine N-oxide-BF₂CF₃ complexes and their fluorescence properties.

作者信息

Nishida Tomoaki, Fukazawa Aiko, Yamaguchi Eriko, Oshima Hiroya, Yamaguchi Shigehiro, Kanai Motomu, Kuninobu Yoichiro

机构信息

Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan).

出版信息

Chem Asian J. 2014 Apr;9(4):1026-30. doi: 10.1002/asia.201301688. Epub 2014 Feb 12.

Abstract

Pyridine N-oxide-BF2CF3 and -BF2C2F5 complexes and their derivatives were synthesized. Most of the complexes show fluorescence both in solution and in the solid state. By expanding the π-conjugated skeleton, the color of the fluorescence could be changed dramatically. A fluorophore with a high solvent dependency could also be produced. Since such compounds can be synthesized on a gram scale in high yield, and are stable to oxygen, water, and heat, the complexes hold great potential as organic functional materials.

摘要

合成了吡啶氮氧化物 - BF₂CF₃和 - BF₂C₂F₅配合物及其衍生物。大多数配合物在溶液和固态中均显示荧光。通过扩展π共轭骨架,荧光颜色可发生显著变化。还可制备出对溶剂依赖性高的荧光团。由于此类化合物能够以高收率克级规模合成,并且对氧气、水和热稳定,这些配合物作为有机功能材料具有巨大潜力。

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