Graduate School of Frontier Biosciences, Osaka University, 1-3 Yamada-oka, Suita, Osaka 565-0871 (Japan).
Chemphyschem. 2014 Mar 17;15(4):642-6. doi: 10.1002/cphc.201301115. Epub 2014 Feb 12.
Differently colored fluorescent Pt nanoclusters (NCs) are easily prepared using polyethyleneimine as the stabilizing ligand and environmentally friendly L-ascorbic acid as the reducing agent. The quantum yields of the blue- (1:5), green- (1:20), and yellow-emitting (1:25) NCs are 4 %, 11 %, and 7 %, respectively. The fluorescent Pt NCs show excellent photostability and are sensitive to Co(2+) ions (with a detection limit of 500 nM).
不同颜色的荧光 Pt 纳米团簇(NCs)可以很容易地通过使用聚乙烯亚胺作为稳定剂和环境友好的 L-抗坏血酸作为还原剂来制备。蓝色(1:5)、绿色(1:20)和黄色发射(1:25)NCs 的量子产率分别为 4%、11%和 7%。荧光 Pt NCs 具有优异的光稳定性,并且对 Co(2+)离子敏感(检测限为 500 nM)。