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超疏水/超亲油棉的制备及其在油水分离领域的应用。

Fabrication of superhydrophobic/superoleophilic cotton for application in the field of water/oil separation.

机构信息

Key Laboratory of Bio-based Material Science and Technology, Ministry of Education, Northeast Forestry University, Harbin 150040, China.

Key Laboratory of Bio-based Material Science and Technology, Ministry of Education, Northeast Forestry University, Harbin 150040, China.

出版信息

Carbohydr Polym. 2014 Mar 15;103:480-7. doi: 10.1016/j.carbpol.2013.12.022. Epub 2013 Dec 14.

Abstract

Cotton with superhydrophobic and superoleophilic properties had been successfully fabricated for application in the field of oil/water separation by the combination of SiO2 nanoparticles on cotton fiber surface and subsequent octadecyltrichlorosilane modification. The as-prepared cotton could be used to selectively absorb various common oils and organic solvents up to above 50 times of its own weight while repelling water completely. The absorbed oils were easily collected by a simple vacuum filtration, and the recovered cotton could be reused for several cycles while still keeping high absorption capacity. Moreover, the as-prepared cotton was simply spun into cloth, which not only could be tailored to the water-repellent clothing but also could be used in the oil/water separation filter system. The results presented in this work might provide a simple, low-cost and environment friendly approach for application in the field of water/oil separation.

摘要

通过在棉纤维表面结合二氧化硅纳米粒子并随后进行十八烷基三氯硅烷改性,成功制备出具有超疏水和超亲油性能的棉花,可用于油水分离领域。所制备的棉花可选择性地吸收各种常见的油和有机溶剂,最高可达其自身重量的 50 倍以上,同时完全排斥水。通过简单的真空过滤可以很容易地收集吸收的油,并且回收的棉花可以重复使用几个循环,同时仍然保持高吸收能力。此外,所制备的棉花被简单地纺成布,不仅可以定制成防水服装,还可以用于油水分离过滤系统。本工作中呈现的结果可能为应用于油水分离领域提供了一种简单、低成本和环保的方法。

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