柱状液晶相和阳离子铂（II）配合物的机械变色性。
Columnar liquid crystallinity and mechanochromism in cationic platinum(II) complexes.
机构信息
Department of Chemistry, Massachusetts Institute of Technology , Cambridge, Massachusetts 02139, United States.
出版信息
J Am Chem Soc. 2014 Feb 26;136(8):2952-5. doi: 10.1021/ja4114352. Epub 2014 Feb 17.
PMID:24533433
Abstract
Cationic square planar Pt(II) complexes are reported with high degrees of intermolecular association. These complexes display thermotropic columnar liquid crystalline behavior in spite of having only a single side chain. Crystals undergo mechanochromic transformations that can be reversed with solvent.
摘要
报道了具有高度分子间缔合作用的阳离子四面体形 Pt(II) 配合物。这些配合物尽管只有一个侧链，但仍表现出热致柱状液晶行为。晶体经历机械变色转变，可通过溶剂进行反转。
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