Hosseinnejad Tayebeh, Ebrahimpour-Malmir Fatemeh, Fattahi Bahareh
Department of Chemistry, Faculty of Physics & Chemistry, Alzahra University Vanak Tehran Iran
RSC Adv. 2018 Mar 29;8(22):12232-12259. doi: 10.1039/c8ra00283e. eCollection 2018 Mar 26.
In recent years, metal complexes of organo 1,2,3-triazole click-derived ligands have attracted significant attention as catalysts in many chemical transformations and also as biological and pharmaceutical active agents. Regarding the important applications of these metal-organo 1,2,3-triazole-based complexes, in this review, we focused on the recently reported investigations of the structural, electronic, and spectroscopic aspects of the complexation process in transition metal complexes of 1,2,3-triazole-based click ligands. In line with this, the coordination properties of these triazole-based click ligands with transition metals were studied several quantum chemistry calculations. Moreover, considering the complexation process, we have presented comparative discussions between the computational results and the available experimental data.
近年来，有机1,2,3 - 三唑点击衍生配体的金属配合物作为许多化学转化反应中的催化剂以及生物和药物活性剂受到了广泛关注。鉴于这些基于1,2,3 - 三唑的金属有机配合物的重要应用，在本综述中，我们重点关注了最近报道的关于1,2,3 - 三唑基点击配体的过渡金属配合物络合过程的结构、电子和光谱方面的研究。与此相符的是，通过一些量子化学计算研究了这些基于三唑的点击配体与过渡金属的配位性质。此外，考虑到络合过程，我们对计算结果与现有实验数据进行了比较讨论。
